New stainless steel can survive conditions for hydrogen production in seawater

https://www.sciencedaily.com/releases/2026/05/260510030950.htm

by HardwareLust • 2 months ago

315 147 2 months ago

https://www.sciencedirect.com/science/article/abs/pii/S13697...

kadoban• 2 months ago

This second shield helps protect the steel in chloride containing environments up to an ultra high potential of 1700 mV.

Uh, dumb question, how is 1.7 volts "ultra high potential" ? Is that even enough to do electrolysis like they're talking about?

ajb• 2 months ago

I think that may not be the potential used for electrolysis, but the chemical potential of the saltwater-metal boundary. But hopefully someone more knowledgeable will comment.

manarth• 2 months ago

Galvanic corrosion typically happens at 0.5V (and as low as 0.15V in salt-water); 1.7V is "ultra high potential" in comparison with normal corrosion thresholds.

Tuna-Fish5• 2 months ago

The potential needed for electrolysis of water is 1.23V in theory, in practice a bit more to overcome inefficiencies. 1.7V is enough.

smusamashah• 2 months ago

That is what makes the finding so striking. Manganese is usually not viewed as a friend of stainless steel corrosion resistance. In fact, the prevailing view has been that manganese weakens it.
"Initially, we did not believe it because the prevailing view is that Mn impairs the corrosion resistance of stainless steel. Mn-based passivation is a counter-intuitive discovery, which cannot be explained by current knowledge in corrosion science. However, when numerous atomic-level results were presented, we were convinced. Beyond being surprised, we cannot wait to exploit the mechanism," said Dr. Kaiping Yu, the first author of the article, whose PhD is supervised by Professor Huang.

This is the Cannot be explained bit

adrian_b4• 2 months ago

A bonus is that manganese is one of the cheapest metals, so this method for increasing the corrosion resistance of stainless steel in salted water and oxidizing conditions is very inexpensive.

MSFT_Edging2• 2 months ago

which cannot be explained by current knowledge in corrosion science

The three stooges effect I see. Too many corrosive elements, they stop each other from getting through the door.

janderson215• 2 months ago

This is great. Any other dynamics in which The Stooges Effect is present?

wnevets• 2 months ago

I was thinking of the Mr Burns sickness bit which references the stooges [1]

[1] https://www.youtube.com/watch?v=aI0euMFAWF8

abduhl• 2 months ago

> Mn-based passivation is a counter-intuitive discovery, which cannot be explained by current knowledge in corrosion science.

This statement sounds like the type of language one uses when trying to get a patent.

adrian_b4• 2 months ago

The part with "cannot be explained by current knowledge" is an exaggeration, because the abstract of the research article explains it very well, based on the current knowledge.

However, "a counter-intuitive discovery" is true. Manganese is frequently used in stainless steels, but only as a cheap substitute for nickel, when this is considered as giving up the superior resistance to corrosion provided by nickel in exchange for the low cost provided by manganese.

The counter-intuitive result of the research is that there are circumstances when manganese provides improved corrosion protection, not only a lower cost.

The reason why this has not been discovered earlier is that manganese alone does not protect against corrosion, but only in an appropriate combination with chromium, when chromium protects both the steel and the manganese at lower electric potential differences, while manganese protects both the steel and the chromium at higher electric potential differences.

hcknwscommenter• 2 months ago

Will be interesting to see if, in hindsight, there are clues to this in the preexisting literature that we just hadn't quite recognized.

nradov2• 2 months ago

This is one of the areas where AI will accelerate scientific research, by scanning through the journal archives to make connections that no one had noticed before.

RugnirViking2• 2 months ago

this kind of headline is bad for our collective souls; I know raging against the clickbait is old hat but seriously, this is ridiculous. Materials science is surely interesting enough to a reader of science direct without being SHOCKED and APPALLED all the time

RugnirViking2• 2 months ago

for reference, the title on the article itself is “Cannot be explained” – New ultra stainless steel stuns researchers

pfdietz16• 2 months ago

Hacker News readers hate this one weird trick!

pjc504• 2 months ago

So apart from the clickbait, the reason why this is interesting is because it's a limiter for the often cited idea of clean green hydrogen from electrolyis. The current use of titanium and precious metals is, obviously, really expensive, so it's uneconomical to build something that only runs on "spare" electricity.

londons_explore• 2 months ago

I don't think the efficiency or longevity of electrolysis equipment is the limiting factor...

The limiting factor is that natural gas is very cheap and cracking it to make blue hydrogen is really easy at scale, and gives off CO2 which is useful for injection into wells to increase production. That sets a price ceiling of hydrogen.

At the other end of the scale, there are batteries to store 'free' electricity and resell later. That sets a floor price of electricity.

Between the floor price of the input and ceiling price of the output, there is no room for electrolysis, even at 100% efficiency, unless government policies mandate it or restrict batteries or blue hydrogen.

whizzter• 2 months ago

There's one case, rural areas often have abundant energy sources (hydro, wind,etc) but few consumers, in Northern Sweden f.ex. a lot is produced but there's a lot of losses in transporting the energy south.

Now, yes, as long as natural gas is cheap(inbetween US or Soviet wars) it'll probably be the core for hydrogen, however batteries won't help much in the north since the transmission rather than usage is the cap even with batteries so excess production could be redirected towards hydrogen production.

leonidasrup5• 2 months ago

Sometimes the price of natural gas is even negative, there is too much of it.

"Natural gas at Texas’s Waha hub is trading at negative $7.05 per million British Thermal Units, hitting a record low of negative $9.52 on April 15."

https://www.barrons.com/articles/natural-gas-texas-negative-...

There are different kinds of water electrolysis equipment, with different capital expenditure and operating expenses.

"Alkaline electrolyzers are cheaper in terms of investment (they generally use nickel catalysts), but least efficient. PEM electrolyzers are more expensive (they generally use expensive platinum-group metal catalysts) but are more efficient and can operate at higher current densities, and can, therefore, be possibly cheaper if the hydrogen production is large enough."

https://en.wikipedia.org/wiki/Electrolysis_of_water#Efficien...

Anything using platinum-group metals will be very expensive. Therefor catalytic converters in cars use very little platinum-group metals.

"The amount of palladium in a converter can vary, but it is typically around 2-7 grams." https://vehiclefreak.com/how-much-palladium-is-in-a-catalyti...

Tuna-Fish5• 2 months ago

Reducing the capital cost of electrolysis is extremely good, because it makes plants that only produce when electricity is cheap (midday in sunny climes, when wind is blowing in the Nordics) more feasible.

If this works out at scale (lots of problems can be found between a lab discovery and mass production), this is legitimately a very good thing for renewables.

pjc504• 2 months ago

unless government policies mandate it or restrict batteries or blue hydrogen

Yes, but I think this the most likely outcome. Natural gas is only cheap in certain areas, and the past few years have made everyone very, very aware of the geopolitics involved in getting hold of it. While global warming is not going away, and I question the extent to which CCS actually happens with blue hydrogen.

Batteries are capital equipment in the same way as electrolysers are. They're great at short term storage, but medium-term is still a bit more of an issue. "Restrict batteries" is obviously not on the table except for stupid retail corner cases where utilities have captured the regulator.

There's a potential market for lots of green H2 in Haber nitrogen, metals refining, and synthetic jet fuel etc, but only if the cheap CO2 emitting option is priced out or banned, or H2 electrolysers get comparable capital prices to battery storage.

BiteCode_dev• 2 months ago

With solar sometimes producing a lot of energy when you don't need it or can't store it, having a cheap hardware to produce hydrogen from it is quite nice.

Natural gaz may be cheap, but you can't beat free.

For this setup, the price of the hardware was a limiting factor.

pfdietz16• 2 months ago

Even without natural gas, hydrogen as a general energy storage medium competes against thermal storage. The round trip for this (electrical energy back to electrical energy) can be as good as hydrogen, and the storage medium can be literally dirt cheap, cheap enough that seasonal storage looks like it makes sense, if the design is brutally focused on cost optimization.

Here, corrosion of steel is also part of the problem, as you are burying steel pipes in piles of hot dirt.

bell-cot• 2 months ago

The limiting factor is that natural gas is very cheap and cracking it to ...

Another, or perhaps related, limiting factor is just how difficult hydrogen is to handle safely - compared to natural gas, batteries, or other alternatives - https://en.wikipedia.org/wiki/Hydrogen_safety. And it does not take many surprise explosions & fires to give a technology a bad rep. Especially when people feel there are obviously-safer alternatives.

Gibbon1• 2 months ago

One interesting use is hydrogen to feed microbes. The driver potentially is solar panels produce 30-100 times more energy an acre than corn. So what if you use solar to produce hydrogen to feed microbes which then produce various feed stocks using nitrogen and CO2 from the air.

SwtCyber3• 2 months ago

Yes, although I'd still want to see how much of total delivered hydrogen cost this actually moves

ritzaco• 2 months ago

@dang maybe we could have the title changed to something like

"Hong Kong researchers develop corrosion-resistant steel for seawater hydrogen electrolysis"

greenbit• 2 months ago

I'd click on that

tomhow2• 2 months ago

Thanks! That's too long (limit is 80 chars) but I came up with something that fits. Feel free to suggest something better.

sveme• 2 months ago

I think the seawater bit is really relevant here. Only understood the importance of this when I saw the seawater part.

voxadam• 2 months ago

You just know that engineers and management in Toyota's delusional hydrogen division are salivating.

adrian_b4• 2 months ago

Nope.

Splitting water into free hydrogen and oxygen is important because it is an essential step for using electrical energy in the chemical and metallurgic industries.

For long term energy storage, free hydrogen is not a good solution, but it can be used to synthesize hydrocarbons, which are suitable for long term energy storage or for aerospace transportation.

Even with abundant and cheap dihydrogen, using it for energy storage in vehicles is a bad idea.

kshahkshah• 2 months ago

They said “delusional”

foobarbecue• 2 months ago

How does this refute the comment you replied to? That comment was implying that Toyota Mirai et al are ill-advised, so seems like your "nope" should be a "yep."

hobofan• 2 months ago

They are not delusional.

Japanese car manufacturers were late to EVs, and in order to prevent a gap in the market where EV-first competitors can steal market share from them, they lobby the government to subsidize and create a new market segment in the form of hydrogen cars. There they have a head start via some latent research and more reuse of ICE car platforms. I'm sure the hydrogen division is well aware that they are doing research on a dead-end technology (at least for the automotive sector).

The exact same thing happened in Germany. In 2020 there was a huge push from politicians to push more hydrogen technology to distract from the fact that German car manufacturers were lagging behind, as well as general missed initiatives for renewable energy. Now, 6 years later those initatives are deader than ever.

UltraSane• 2 months ago

Hydrogen is simply a really bad fuel for cars. It is hard to transport and store liquid hydrogen

pfdietz16• 2 months ago

You're explaining the practical consequences of their delusion, but delusion it remains. Hydrogen for cars isn't going to work to save them, even with the lobbying. Granted, they were probably screwed anyway, so they had no good options.

chupasaurus• 2 months ago

Japanese car manufacturers were late to EVs ... they lobby the government to subsidize and create a new market segment in the form of hydrogen cars

Production of Toyota Prius started 28 years ago.

boppo1• 2 months ago

Can anyone give me a semi-technical reason on why the hydrogen division are delusional? I'm actually convinced of it "osmotically", but I just don't know enough about it. I've got chem 101 behind me but otherwise I'm a finance & tech guy. It would be nice to actually understand why it can't be done though.

craftkiller2• 2 months ago

Assuming we're talking about cars/trucks, one major reason hydrogen doesn't make sense is efficiency: https://cdn.motor1.com/images/mgl/OrLRA/s1/efficiency-compar...

If we manage to get enough solar such that energy essentially becomes infinite then the inefficiency would no longer matter. Otherwise, it would only make sense in vehicles that require high energy density like airplanes.

1970-01-013• 2 months ago

Hydrogen leaks too much. You cannot transfer it without spilling a good chunk, around 8 percentage of it into the atmosphere. Now match that loss by your long term refuel needs and you'll simply run out of it. It can't scale up to anywhere near what would be considered a replacement technology for EVs.

dvh• 2 months ago

So does carbon, no?

SwtCyber3• 2 months ago

Sometimes, but carbon has its own failure mode: at high anodic potentials it can oxidize

SwtCyber3• 2 months ago

The "cannot be explained" headline is a bit much, but the underlying result is genuinely interesting

bilsbie• 2 months ago

Dupe: https://news.ycombinator.com/item?id=48109497

drdrek• 2 months ago

Material science is so cool

pfdietz16• 2 months ago

A problem I'd have with seawater electrolysis is production of undesirable chlorine compounds: hypochlorite or elemental chlorine.

Or maybe there are uses for these? Releasing chlorine (diluted!) into the atmosphere might be a way to accelerate the scrubbing out of methane. Chlorine is photolysed by sunlight into chlorine atoms, which immediately react with methane.

nyeah4• 2 months ago

Unfortunately, some products of methane-chlorine reaction are much less desirable than methane.

pfdietz16• 2 months ago

If you react large amounts of methane and chlorine, the methyl radicals will react with molecular chlorine to make methyl chloride. But if the methane and chlorine are dilute, as they would be here, the methyl radicals with react with something else (like oxygen) first.

Destruction of methane by chlorine has been observed naturally, for example after the Hunga Tonga-Hunga Ha'apai eruption in 2022 (although the chlorine-mediated destruction there was less than methane injected by the volcano itself.)

https://www.sciencealert.com/a-massive-volcano-destroyed-met...

m4rtink• 2 months ago

Don't they also react also with about anything else ? I would be a bit worried what else "gets eaten" if something as reactive as chlorine is released into the atmosphere on a wider scale.

pfdietz16• 2 months ago

They'd also react with other hydrocarbons, also extracting hydrogen atoms. But that's ok too -- those hydrocarbons act as sinks for hydroxyl radicals, reducing the rate of methane destruction.

NortySpock• 2 months ago

If we're talking seawater already, why not dilute it with seawater down near the ocean floor and have it react with some rocks or something? Why put chlorine gas directly into the atmosphere?

pfdietz16• 2 months ago

To destroy methane, which is a strong greenhouse gas.

asa4002• 2 months ago

Very interesting. Highly corrosion resistant "unconventional" steels have become somewhat popular in cutlery, with steels like LC200N, H1/H2, and MagnaCut. LC200N and H1/H2 in particular can be left in body of water uncoated/unpainted and come back in a year and they'll be fine. Obviously that's a different setting than electrified seawater for hydrogen production, though. So much cool materials science happening!

amluto• 2 months ago

I'm not at all convinced that the highly corrosion resistant knife/tool steels you mention are actually especially high on the corrosion resistance scale -- I think they may just be excellent for a tool steel.

If you look at the knifesteelnerds article on H1 (https://knifesteelnerds.com/2019/06/24/h1-steel-how-it-works...), you'll find that it's an austentitic alloy (which is highly unusual for any sort of tool steel), and that it seems like it's likely a somewhat less corrosion resistant than usual variant on steels like 301 or 304. And the rather common stainless alloy used for non-tool applications where high levels of corrosion resistance is 316, which is more corrosion resistant than 304.

In any case, this new alloy is weird -- it seems like it specifically has excellent resistance to electrochemical corrosion when it is used as an anode, which is not what people usually use stainless steel for :)

asa4002• 2 months ago

Entirely possible! I'm definitely not an expert. I own a few of these (LC200N and Magnacut) and I can confirm they've held up well in my own use of getting wet/dirty/etc. vs. other tool steels I have. Where they stack up against non-tool steels or steels not commonly used in cutlery, I couldn't say.

That said, I have heard plenty of anecdotes confirming these properties from other folks. People losing a knife in a stream or field and then finding it the following year, etc.

In any case, this new alloy is weird -- it seems like it specifically has excellent resistance to electrochemical corrosion when it is used as an anode, which is not what people usually use stainless steel for :)

100%. Probably almost no crossover into cutlery, but super cool regardless!

aidenn0• 2 months ago

Yes. For example, nitrogen alloyed steels like Vanax or LC200N (both of which are more corrosion resistant than the other alloys mentioned by GP) aren't particularly corrosion resistant in the total space of stainless steels, they are just very corrosion resistant as compared to how hard (and/or tough) they are.

[edit]

I should also point out that the two alloys I mentioned are not particularly hard or tough for a knife steel.

nickburns• 2 months ago

https://en.wikipedia.org/wiki/Hydrogen#Applications

briandw• 2 months ago

I truly do not understand the fixation with hydrogen as a fuel. Compressing H2 to store it requires around half of the total energy that you can expect to get from its final application. Add in production losses and the difficulty in storage and handing, its always much worse than batteries.

I can see the argument for use in industrial processes like steel manufacturing as a reducing agent, but not as a power source.

Brian_K_White• 2 months ago

I truly do not understand the fixation with trying to use batteries in applications that really need a fuel.

Tuna-Fish5• 2 months ago

In a lot of places in the world, the marginal cost of electricity is zero, if your capital costs are low enough to only purchase when there is excess wind.

The cost of batteries for long-term storage is still prohibitively high. In contrast, large hydrogen (or methanol, etc further products) are relatively cheap to store.

Those two things put together is pretty much it. There is massive room for additional wind capacity in northern europe (and solar in north africa, etc). In order for constructing that additional capacity to make any sense, there needs to be more demand that can idle for ~2/3rds of the time, and make economic sense to run a third of the time. In these conditions, the roundtrip efficiency is an entirely uninteresting statistic, and the capital cost of capacity is what matters.

KennyBlanken2• 2 months ago

How strange utility grids are spending on BSS and not hydrogen infrastructure.

How strange utility grids are spending on HVDC transmission and not hydrogen infrastructure.

HN commenters should ring up their local electrical grid operators and set them straight /s

Also, if you have extremely low cost of electricity: you build manufacturing nearby that needs massive amounts of energy, like metal refineries. Or you subsidize electric transport.

You don't pour money into a fuel that is a logistical headache and a half, a fuel that nobody uses, and can only be converted back into electricity with the standard terrible internal combustion / turbine efficiencies.

fisherjeff• 2 months ago

Well green hydrogen is also a necessity if you want to make carbon-neutral synthetic hydrocarbon fuels.

alephnerd2• 2 months ago

I truly do not understand the fixation with hydrogen as a fuel

Not everything is about "muh EV".

There is a reason that countries that have built significant Solar PV and Wind Turbine manufacturing capacity like China, Germany, SK, Japan, and India have also been investing in H2.

H2 as an energy market helps subsidize additional H2 usecases such as Ammonia/NH3 production for fertilizers (this has become critical due to the ongoing Iran War), steelmaking via H2 direct reduced/sponge iron, and (for China and India) coal gasification.

Additionally, REEs and critical minerals have increasingly become a bottleneck so additional options is good to have depending on the country, which is a major reason Japan heavily invested in hydrogen along with sodium solid state battery R&D.

And finally, the brutal truth is no major country actually cares about climate change - they care about energy security. Most larger countries have the ability to afford the externalities that arise from climate change, the three largest CO2 emitters in the world (China, US, India) are seeing CO2 emissions rise (mind you at a reduced rate, but still unsustainable from a climate change perspective), and in China and India's case continue to leverage coal as an energy security tool especially after the Iran War supply chain crisis highlighted the criticality of coal gasification for the fertilizers and agriculture.

KennyBlanken2• 2 months ago

You don't need hydrogen to smelt, refine, recycle, whatever, metal.

You build an electric arc furnace.

dec0dedab0de• 2 months ago

I think the best argument for hydrogen is for automobiles. Existing cars can be converted to use it, doesn't spray pollution all over the city, and can be refilled quickly unlike a battery.

SoftTalker3• 2 months ago

Can existing cars be converted? Yes for CNG/methane or LPG/propane but not sure I've heard of Hydrogen conversions. Wikipedia says conversion to Hydrogen requires:

... hardened valves and valve seats, stronger connecting rods, non-platinum tipped spark plugs, a higher voltage ignition coil, fuel injectors designed for a gas instead of a liquid, larger crankshaft damper, stronger head gasket material, modified (for supercharger) intake manifold, positive pressure supercharger, and high temperature engine oil.

For CNG or LPG conversion I think some fuel system components need to change but the rods, valves, head gasket, etc. are all unchanged.

My guess as to the reason is that hydrogen will basically detonate in the cylinder, whereas methane or propane will burn more like gasoline.

SoftTalker3• 2 months ago

It's basically a battery. It's not a power source, it's energy storage. If the energy is cheap enough (e.g. solar) inefficiencies don't matter as much.

DoctorOetker• 2 months ago

with hydrogenotrophs you can create food (all amino acids) from solar hydrogen, supposedly about 10% more efficiently, this could return a lot of arable land for wilding, solar farms, housing, ...

Imagine dividing farmland by 10x by feeding hydrogenotrophs with solar H2.

spauldo• 2 months ago

I seem to remember Iceland was looking hard into hydrogen for their fishing fleets. They have to import Diesel fuel but they've got geothermal running out of their ears.

I haven't checked to see how that went, but it sounded like the perfect test case for hydrogen's viability.

benj111• 2 months ago

While interesting is this ever going to be actually needed? Unless hydrogen is going to be used in a decentralised fashion, which seems unlikely, water can simply be saved from recombining hydrogen and oxygen. So you only ever need a finite amount of water.

Plus there's also futures where harvesting salt / lithium from seawater leaves clean ish water as a by product, or a future where when it's sunny, just boil water to evaporate it with nearly free solar, then electrolyse it. And you'd need near free electricity to make this economic.

lukeinator42• 2 months ago

This would be great for other use cases too like climbing bolts and anchors in coastal areas. Lots of areas are switching to titanium glue-ins which are expensive, but I wonder if this could enable more affordable option. A climber recently died in Greece after multiple bolts failed: https://gripped.com/news/rock-climber-dies-in-kalymnos-after...

cgh• 2 months ago

Good point, not only is titanium expensive but the glue-in part is tricky to get right as the glue has to completely surround the bolt. Not only that, but early efforts at titanium rebolting sometimes didn’t use glue at all. In Thailand, I pulled out some titanium bolts with my fingers because they weren’t glued in.

kansface• 2 months ago

3 10mm bolts failing simultaneously after two decades (on direct it seems) is unexpected! If it were an installation problem, I can’t imagine it would take that long and that they’d all go at the same time. Ditto for corrosion… people take victory whips all the time.

IAmBroom4• 2 months ago

All three bolts at critical level. A massive strain happens along. They pop: one, two, three!

It's not that unexpected.

inasio• 2 months ago

Stayed a few times in a place exposed to constant breeze from a tropical Pacific coast beach, and learned that stainless steel doesn't really last very long there. Everything stainless steel-based (fixtures, fridges, handles) rusts in a few years. I'd bet there's a market for upscale alloys

annoyingnoob• 2 months ago

Depends on the alloy. Just a guess, you had 304 stainless which will rust fairly easily in saltwater. 316 would last longer. Also it can be tricky to retain the corrosion resistance when welding stainless, your part might corrode first at weld points.

https://www.nemaco.com/blogs/304-vs-316-stainless-steel-diff...

1970-01-013• 2 months ago

If this is just a second layer, then it cannot be welded during on-site manufacturing nor for repair. If that is true, this isn't a major breakthrough for maritime. Things-of-scale need to be welded to be manufactured at said scale.

dr_dshiv• 2 months ago

Imagining the giant solar lily pads that can create enormous hydrogen platforms in the sky.

hannob• 2 months ago

Making hydrogen from seawater is not an actual problem that needs solving.

The problem with hydrogen electrolysis is its energy requirements to split water. The energy requirements for the desalination of water before that is a rounding error. It's not worth the hassle to develop electrolyzers that can deal with seawater.

nickff• 2 months ago

Desalination is not the only application of seawater electrolysis.

SoftTalker3• 2 months ago

"The same research program previously produced anti-COVID-19 stainless steel in 2021"

WTF is "anti-COVID-19 stainless steel" I wonder.

Edit: Turns out it's a high-copper alloy that has antiviral properties.

lucaspiller• 2 months ago

Is there any progress being made on cars so they are less susceptible to rust? In my country that's the main reason why vehicles are scrapped, engines can be repaired easily enough, but when various suspension parts are corroded and need replacing it's not worth fixing anymore.

As I understand one of the reasons against using materials like stainless steel or other alloys for cars is that is is harder to work with, but most new cars today are written off - rather than being repaired - after even minor accidents, so that doesn't really seem like it's a realistic concern.

simulator5g• 2 months ago

This is basically a solved problem. Saturn used plastic body panels on cars for a while. These cars had some painted metal parts that were protected by the plastic, and would never rust, because painted metal only rusts after the paint is compromised. Saturn went bankrupt and no one has been doing this. I suspect that it is really bad for a car company's bottom line because it lets people keep their car instead of buying a new one.

Also, you can coat your car underbody in an oil based coating 1-2x a year, and it won't rust. Its just an annoying chore that most people don't want to even think about.

New stainless steel can survive conditions for hydrogen production in seawater

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