There was an unintentional fork on August 15, 2010, when "[an] attacker exploited [an] integer overflow bug that permitted an attacker to create several billion bitcoins". [source][0]
There was an unintentional fork on March 12, 2013 caused by previously disallowed number of tx inputs (?) as resolved by [BIP50][1].
[0] https://blog.blockchain.com/2016/02/26/a-brief-history-of-bi... [1]: https://github.com/bitcoin/bips/blob/master/bip-0050.mediawi...