Certain libraries (both standard and 3rd party) perform significantly better - in part because there appear to be some performance improvements in 2.6 which 3.0 also benefits from.
Standard ElementTree (pure python) is roughly 40% faster in Python 3 than in 2.5. cElementTree is likewise about 40% faster. A templating package I use runs 3 times slower on 2.5 than on 2.6 and 3.0 (similar performance on 2.6 and 3.0).
Bearing in mind that optimization work will follow on, I believe being "fast enough" is a good achievement for Python 3 and I'm personally pleased that performance will not be a roadblock for my own adoption. Where I can live on the bleeding edge I plan to.